COVER PAGE

TITLE:

ENERGY CONVERSION IN BIOLOGICAL SYSTEMS

AUTHORS:
Nancy Sanders, Science Division, Northeast Missouri State University, Kirksville, MO 63501, (816) 785-4619

Todd Bennethum, Department of Biological Sciences, 1392 Lilly Hall, Purdue University, West Lafayette, IN 47907-1392, (317) 494-8107

Bruce Parker, Department of Biology, Utah Valley State College, 800 W. 1200 So., Orem, UT 84058-5999, (801) 222-8000 x.8650

For more info: contact Bruce Parker

KEYWORDS:
energy, cell respiration, chemical reaction, carbon dioxide production, oxygen consumption, glucose, work, food potential energy, ATP, energy conversion

ABSTRACT:
Energy conversion/transformation and its application to biological systems is a difficult subject for many students. The goal of this lab is to make a connection between potential energy stored in present in chemical bonds of organic nutrient molecules, and biological "work" performed by organisms as a result of ATP production in cellular respiration. Demonstrations, concept mapping, group discussions, and investigation are all used to enhance learning.

FAIR USAGE:
BIOLAB and LABSHOP are supported by NSF. The teaching materials placed on BIOLAB may be freely copied and disseminated for all noncommercial educational activities provided that appropriate credit is given to the authors, this source, and its NSF support.

INSTRUCTORS GUIDE

Background Information

Objectives:
Students often have misconceptions and misunderstandings about energy, energy conversions/transformations, and energy in biological systems. The primary objective of this lab is to reinforce the concept of energy, and to explore its relationship to biological work, via experimentation with plant and animal cellular respiration.

Student successfully completing this exercise should be able to:

- Define energy as it applies to biological systems. This definition should include the concepts of work, energy transformation, potential energy, and heat.

- Describe cellular respiration and how this process converts energy to useable forms. The description should include the input components and the output products of respiration.

- Understand and be able to design the experiments to test for the those measurable aspects of cellular respiration and the factors which influence respiration.

Concepts:
The focus of the lab is the concept of energy transformation. Cellular respiration is the mechanism by which chemical energy is converted from one form to a more usable form, with a release of a certain amount of heat. Energy is defined as the capacity to do work and students can be directed to envision energy as being necessary for biological work. Biological work includes the simple maintenance of life and energy comes from food/nutrient molecules which are broken down. Stored (potential) energy is transformed to be used to fuel biological processes. Nearly all of the energy used to maintain life is ultimately derived from the sun.

Factual background:
Organisms need energy to perform many of the essential functions of life, such as growth, repair, movement, reproduction, and transport. Plants and other primary producers transform energy from solar or lithochemical sources into storage products that are used as energy sources ("food") by consumer organisms. Energy needed to do biological work comes from the potential energy stored in chemical bonds in these food or nutrient sources. Respiration is the conversion of chemical bond energy in nutrient molecules into forms directly usable by the cell, such as ATP. Respiration can be aerobic (oxygen) or anaerobic (without oxygen). This lab is designed to explore the subject of aerobic respiration only. However, some discussion of anaerobic respiration may be useful as well in the initial portion of the lab.

In aerobic respiration, a molecule of glucose is broken down completely to CO2 and water, with the assistance of enzymes, according to this basic equation:

C6H12O6+6O2 -> 6CO2+6H2O+energy (ATP)
The potential energy in the glucose molecule is released in glycolysis (not an oxygen requiring step), the Krebs Cycle and the electron transport chain. Refer to a textbook for a detailed discussion of these processes.

The occurrence of cellular respiration in an organism can be demonstrated in several ways. Some energy is give off as heat, and some biological systems use energy to reproduce light. The amount of glucose used can be determined, and the amount of oxygen consumed can be measured. In this laboratory, cellular respiration will be determined by measuring CO2 production. In aquatic systems, CO2 produced during cellular respiration will result in acidification of the fluid medium. Thus, CO2 production can be estimated by monitoring pH changes in the fluid medium. These changes can be measured with high grade litmus paper or, preferable, a calibrated pH electrode.

Bibliography:

Campbell, N.A. (1993) Biology, 3rd Edition. Benjamin/Cummings Publishing Co., Inc., Redwood City, CA, 1190 pp.

Keeton, W.T. and J.L. Gould (1993) Biological Science, 5th Edition. W.W.Norton & Co., New York, NY, 1194pp.

Taylor, M.T. (1993) Student study guide: An introduction to concept mapping for Campbell's Biology, 3rd Edition. Benjamin/Cummings Publishing Co., Inc. Redwood City, CA, 452pp.

Eberhard, C. Saunders general biology laboratory manual to accompany Villee, et al BIOLOGY. Saunders College Publishing, 1990. pp. 64-66. Procedure

We suggest the following introductory demonstration, with no prior discussion of the topic.

1. Bring in a narrow necked bottle (pop bottle works well) containing a white powder (baking soda - sodium bicarbonate). Pour into the white powder a clear liquid (vinegar - dilute acetic acid, concentrated does not work well). (This will go faster if the baking soda is 1st dissolved in water). Place a balloon over the opening of the bottle and capture the gasses emitted - the balloon will inflate rapidly. Shake the bottle a bit to facilitate mixing and increase gas production. Remove the balloon and let it go - it will fly around the room until it is empty. Alternatively, use one of those balloon-powered toys that come in breakfast cereals, etc.

2. Ask the students, "What just happened here?" Try to get them to list as many concepts as possible that they can identify with experimental demonstration they just witnessed. If you and they are already familiar with concept mapping, this is a good opportunity to use it. Try to center (or steer) the conversation around the concept of energy. This is a demonstration of chemical energy in an inorganic system - what about a biological system? Try to get the students to identify the different components in the demonstration and what they might be analogous to in a biological system: white powder - "food", liquid - enzymes to aid in energy transformation, gas - potential (stored) energy (ATP), movement of balloon - using potential energy to do work.

3. An optional exercise at this point is the classic "burn a peanut" demonstration. Light a peanut that is suspended beneath a test tube with a known volume of distilled water. Measure heat production via a temperature change in the water. One calorie (4.2 J) can heat 1g (1 ml distilled water) through 1oC. The energy released by burning the peanut is used to heat the known quantity of water. This demonstration may help lead you from a discussion of inorganic chemical bond energy seen in #1, to biological energy used to work.

4. Demonstrate the need for oxygen to do biological work. Have one student at each table squeeze a tennis ball or racquet ball as rapidly as possible. Have the other students time how long this can be done, and the frequency of squeezes. This can be plotted out for better visualization. Ask the students why they couldn't continue squeezing the ball indefinitely. Relate this to the basic formula for cellular respiration- and the concept of aerobic vs. anaerobic cellular respiration. Also, encourage the students to connect the idea that work is exhibited in the maintenance of the structure of living things. An alternative to this demonstration is to have the students list some ways that they do biological work, such as exercise and have each group analyze the rate at which the work may be maintained. If it can be done in a sensitive manner, it may be interesting to point out the differences between different students and their levels of work capacity. Examples of work might be doing "arm curls" with a small weight, or climbing stairs. Be careful not to be too strenuous or involve students who may present a health risk. As the students analyze the data, encourage them to explore reasons for the decrease in the capacity to work over time. Some explanations may involve depletion of food resources or lack of circulation. The idea of oxygen depletion may crop up and also lead to a discussion on the difference between physiological "respiration" and cellular respiration. Be able to tie the two concepts together.

5. Ask the students to generate a list of the different kinds of organisms which might be expected to use energy and carry-out respiration. The diversity should be useful in pointing to the universal nature of some form of respiration. Continue the class discussion in a large group, or small groups, to cover the topic of cellular respiration - pull out the major concepts mentioned earlier to help the students in hypothesis formulation. Discuss ways of measuring cellular respiration to give the students an idea of how to proceed with actual experimentation. The ideas could include the production of CO2 with the resulting decrease in pH, the release of heat as the energy is lost due to the inefficiency of respiration, or the loss of oxygen in the enclosed system. Which approach the students are allowed or encouraged to pursue will depend on the available equipment. Some discussion as to why the levels of CO2 result in the change in pH is appropriate since many of the students may not connect the ideas. ( CO2+H2O-> H2CO3-> 2H+ + CO3-- ) It may be useful to have them do the classic demonstration of blowing through a straw into lime water or into distilled water containing a pH electrode to show that they are producing the changes simply by their own exhalation of CO2.

6. Experimentation

At this point, provide the students with materials to set up their own experiments to demonstrate the occurrence of cellular respiration. The use of adequate controls should be discussed. We suggest using Elodea for one organism, to reinforce the fact that plant cells also have mitochondria and respire. Other animals may include small aquatic animals such as Daphnia guppies or snails. Demonstrate the use of litmus paper or pH electrodes, if necessary. Be sure to start with water that is pH 7.5-8.0 for best results. Water - use spring water if available. Otherwise, ???...Do not use straight tap water. If the water is below pH 7.5, adjust the pH up with NaOH. Don't use sodium bicarbonate if you are then assaying for a CO2 based pH change. Be careful not to introduce anything which would act as a buffer.

Elodea - ask the students to think about what circumstances would increase respiration in a plant. Test tubes sealed with rubber stoppers work well for Elodea. Some could be placed in the dark and others left in the light for comparison.

Daphnia - Use the bulb end of a cut off, small, disposable (reusable!) plastic pipette for a respiration chamber. We found a pH change of >0.5 pH units with as few as 6 Daphnia in the pipette for 20 minutes.

Larger animals - use an Erlenmeyer flask with a rubber stopper to minimize dead space for gas exchange. Use animals that have not recently been fed (24h for Daphnia, longer for fish and snails) and the shortest possible run times to minimize ammonia production. (This also makes a good discussion topic - what other factors may alter the pH?)

The pH can be monitored over time, and a graph depicting rate of CO2 production generated (change in pH/time).

If time allows, the students may desire to investigate the differences that occur in respiration rates under varying environments for the organisms they are using. They may try varying the temperature, exposure to light versus darkness, increased number of organisms, exposure to mild poisons such as detergents or heavy metals, etc. If Daphnia are used, they may be placed in an ice bath and the decrease in activity noticed and related to respiration. Their recovery once returned to room temperature may also be investigated.

Hints, Suggestions, and Special Instructions

Just to reemphasize some points:

1. Don't use tap water for the experiments.

2. Adjust the pH to 7.5-8.0 starting to see a pH change.

3. Use starved animals to minimize ammonia production.

4. pHydrion papers from Sigma work very well if pH meters are unavailable.

5. Try to limit the surface area of the water as much as possible to reduce the amount of gas exchange which may occur at the air-water interface.

6. Larger organisms like snails or fish may be placed in 100 ml of water to concentrate the CO2 to measurable levels. A stoppered erlenmeyer flask works well.

Materials, Supplies, Recipes, Special Instructions

Materials:
pop bottle, vinegar, baking soda, balloon, peanut, ring stand, clamp, pin, bunsen burner, test tube, distilled water, thermometer, live animals such as Daphnia, guppies, snails , spring water, Erlenmeyer flasks, rubber stoppers, large test tubes, disposable plastic Pasteur pipettes, litmus paper - 3 colour comparison type (or pH meter + pH electrode and pH 2, 7, 10 buffers)

Expected Student Outcomes

Students should have tremendous variations in the rates at which physiological fatigue occurs, but their muscles should show signs of stress within 3-15 minutes.

We have observed easily measurable changes in pH in 15-30 minutes of at least one-half a pH unit and as many as 2 units.

Overall, students should gain the following:

1. An improved understanding of energy, cell respiration, and associated concepts.

2. Reinforce the fact that plants also respire.

3. Build hypothesis formulating and testing skills.

4. Data collection, tabulation, and graphing skills.

5. Practice in writing a lab report.

Time frame

1/2 hour - 1 hour for introduction; 2 hours for the remainder

STUDENT PROTOCOL

Introduction

Today's lab will explore the concepts of energy and cellular respiration. In cellular respiration, chemical bonds (Carbon) are broken to release energy that is stored as ATP. ATP can be used as a source of energy to fuel the metabolic needs of the organism. The metabolic needs constitute biological "work" including transport, reproduction, movement, synthesis, waste removal, and growth.

The initial step in cellular respiration is glycolysis, a series of chemical reactions found in every known living organism. Respiration can proceed without oxygen (anaerobic) or it can be oxygen requiring (aerobic). Aerobic respiration utilizes the Krebs Cycle and electron transport chain to generate ATP. This lab will be concerned only with aerobic respiration. For more detail about glycolysis, the Krebs Cycle and the electron transport chain, refer to your text.

How might cellular respiration be demonstrated and measured? What is the basic chemical reaction for cellular respiration? Cellular respiration in a controlled aquatic system can be estimated by measuring the amount of CO2 produced. An increase in CO2 will result in a decrease in the pH in a closed aquatic system - why? You will choose from a variety of aquatic organisms and use a pH electrode or pH litmus paper to indirectly measure CO2 production by monitoring changes in pH.

Objectives

1. The primary objective is to develop a better understanding of the concepts of energy and cellular respiration, and related concepts.

2. Through this lab you will gain experience in hypothesis formulation, hypothesis testing through direct experimentation, and reporting and discussing results and findings.

3. Through direct experimentation, you will become familiar with cellular respiration in both plants and animals.

Specific Instructions

After an introduction to energy and cellular respiration, a number of organisms will be available for direct experimentation. Try to formulate hypotheses that can be tested with the available materials. What factors might affect cellular respiration in plants? Animals? Why? What will be your control(s)? What data will you collect? Discuss your possible hypotheses with your instructor, and select one that is testable in the allotted time. Proceed with setting up your experiment. Be sure to record your starting times, initial pH, and any behavioral observations. At time intervals you and your instructory decide upon, measure the pH in the fluid medium and record the pH and time on a data table.

Reporting results

A graph of your results can be constructed. What is the dependent variable? The independent variable? How do your results compare with your hypotheses? What were some possible problems with your experimental technique? What are some further questions that might be interesting to address with future experimentation?

Conclusions

Address the following questions:

1. Which of your experiments produced the most dramatic results? Speculate why this might be so?

2. What were some of the major findings of the other groups in the lab?

3. How would you explain cellular respiration to a person with no prior knowledge of the concepts involved?

4. How do your results show that cellular respiration is occuring? What are some other experiments that might be used to demonstrate other aspects of cellular respiration?

5. What are some of the conditions which you might alter which would affect respiration and why? What would be the expected outcome of altering these conditions?